Factors affecting concrete strength
Water/Cement
Ratio
In cement hydration, it has been pointed out
that the density of hardened cement is governed by the water/cement ratio. With
higher w/c ratio, the paste is more porous and hence the strength is
lower. Also, the strength continues to
increase with decreasing w/c ratio only if the concrete can be fully compacted.
For concrete with very low w/c ratio, if no water-reducing agent is employed,
the workability can be so poor that a lot of air voids are entrapped in the
hardened material. The strength can then be lower than that for concrete with
higher w/c ratio. While w/c ratio is the most important parameter governing the
strength of concrete, it is not the only parameter.
Age
and Curing Condition
Provided the concrete is properly cured, the
strength increases with time due to the increased degree of hydration. The 7-day
strength can range from 60 – 80% of the 28-day strength, with a higher
percentage for a lower w/c ratio. After 28 days, the strength can continue to
go up. Experimental data indicates that the strength after one year can be over
20% higher than the 28-day strength. The reliance on such strength increase in
structural design needs to be done with caution, as the progress of cement hydration
under real world conditions may vary greatly from site to site.
Aggregates
For the same w/c ratio, mixes with larger
aggregates give lower strength. This is due to the presence of a weak zone at
the aggregate/paste interface, where cracking will first occur. With larger
aggregates, larger cracks can form at the interface, and they can interact
easier with paste cracks as well as other interfacial cracks. With the same mix
proportion, rougher and more angular aggregates give higher strength than smooth
and round aggregates. However, with
smooth aggregates, a lower w/c ratio can be employed to achieve the same
workability. Therefore, it is possible to achieve similar strength with smooth
and rough aggregates, by adopting slightly different w/c ratios. For a fixed w/c ratio, the strength increases
slightly with the aggregate/cement ratio. This is because aggregates are often
denser than the cement paste. With less paste in the concrete, the overall
density is increased. For normal
strength concrete, the aggregate strength is seldom a concern. However, in the
development of high strength concrete, it is important to select aggregates
with strength higher than that of the hardened paste.
Admixtures
Air-entraining agents
decrease concrete strength by incorporation of bubbles. Set retarding and
accelerating agents affect the early strength development but have little
effect on ultimate strength. Incorporation of mineral admixtures increases
ultimate strength through the pozzolanic reaction.
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