Monday, April 18, 2022

WHAT ARE PROPERTIES OF FRESH CONCRETE?

Definition

Fresh concrete is defined as concrete at the state when its components are fully mixed but its strength has not yet developed. This period corresponds to the cement hydration stages. The properties of fresh concrete directly influence the handling, placing and consolidation, as well as the properties of hardened concrete.

Workability

a) Definition

Workability is a general term to describe the properties of fresh concrete.  Workability is often defined as the amount of mechanical work required for full compaction of the concrete without segregation.  This is a useful definition because the final strength of the concrete is largely influenced by the degree of compaction. A small increase in void content due to insufficient compaction could lead to a large decease in strength.  The primary characteristics of workability are consistency (or fluidity) and cohesiveness. Consistency is used to measure the ease of flow of fresh concrete. And cohesiveness is used to describe the ability of fresh concrete to hold all ingredients together without segregation and excessive bleeding.

 b) Factors affecting workability

Water content: Except for the absorption by particle surfaces, water must fill the spaces among particles. Additional water "lubricates" the particles by separating them with a water film. Increasing the amount of water will increase the fluidity and make concrete easy to be compacted. Indeed, the total water content is the most important parameter governing consistency. But, too much water reduces cohesiveness, leading to segregation and bleeding. With increasing water content, concrete strength is also reduced.

Aggregate mix proportion:  For a fixed w/c ratio, an increase in the aggregate/cement ratio will decrease the fluidity. (Note that less cement implies less water, as w/c is fixed.) Generally speaking, a higher fine aggregate/coarse aggregate ratio leads to a higher cohesiveness.

Maximum aggregate size: For a given w/c ratio, as the maximum size of aggregate increases, the fluidity increases. This is generally due to the overall reduction in surface area of the aggregates.

Aggregate properties: The shape and texture of aggregate particles can also affect the workability.       As a general rule, the more nearly spherical and smoother the particles, the more workable the concrete.

Cement: Increased fineness will reduce fluidity at a given w/c ratio, but increase cohesiveness. Under the same w/c ratio, the higher the cement content, the better the workability (as the total water content increases).

Admixtures: Air entraining agent and superplasticizers can improve the workability.

Temperature and time: As temperature increases, the workability decreases. Also, workability decreases with time. These effects are related to the progression of chemical reaction.

c) Segregation and bleeding

Segregation (separation): Segregation means separation of the components of fresh concrete, resulting in a non-uniform mix. More specifically, this implies some separation of the coarse aggregate from mortar.

Bleeding (water concentration): Bleeding means the concentration of water at certain portions of the concrete. The locations with increased water concentration are concrete surface, bottom of large aggregate and bottom of reinforcing steel. Bleed water trapped under aggregates or steel lead to the formation of weak and porous zones, within which micro cracks can easily form and propagate.

Measurement of workability

 a) Slump test (BS 1881: 102, ASTM C143):  Three different kinds of possible slumps exist, true slump, shear slump, and collapse slump. Conventionally, when shear or collapse slump occur, the test is considered invalid. However, due to recent development of self-compact concrete, the term of collapse slump has to be used with caution.

 b) Compaction factor test (BS 1881: Part 103):  The compacting test was developed in Great Britain in 1947.The upper hopper is completely filled with concrete, which is then successively dropped into the lower hopper and then into the cylindrical mould. The excess of concrete is struck off, and the compacting factor is defined as the weight ratio of the concrete in the cylinder, MP, to the same concrete fully compacted in the cylinder (filled in four layers and tamped or vibrated), mf (i.e., compacting factor = MP/mf). For the normal range of concrete, the compacting factor lies between 0.8 to 0.92 (values less than 0.7 or higher than 0.98 is regarded as unsuitable). This test is good for very dry mixes.  Three limitations: (i) not suitable for field application; (ii) not consistent; (iii) Mixes can stick to the sides of the hoppers.

c) Vebe test (BS 1881: Part 104):  The Vebe consistometer was developed in1940 and is probably the most suitable test for determining differences in consistency of very dry mixes. This test method is widely used in Europe and is described in BS 1881: Part 104. It is, however, only applicable to concrete with a maximum size of aggregate of less than 40 mm. For the test, a standard cone is cast. The mould is removed, and a transparent disk is placed on the top of the cone. Then it is vibrated at a controlled frequency and amplitude until the lower surface of the disk is completely covered with grout. The time in seconds for this to occur is the Vebe time. The test is probably most suitable for concrete with Vebe times of 5 to 30s. The only difficulty is that mortar may not wet the disc in a uniform manner, and it may be difficult to pick out the end point of the test.

d) Ball-penetration test

 A measure of consistency may also be determined by ball penetration (ASTM C360). Essentially, this test consists of placing a 30-lb metal cylindrical weight, 6" in diameter and 4-5/8" in height, having a hemi-spherically shaped bottom, on the smooth surface of fresh concrete and determining the depth to which it will sink when released slowly. During penetration the handle attached to the weight slides freely through a hole in the center of the stirrup which rests on large bearing areas set far enough away from the ball to avoid disturbance when penetration occurs. The depth of penetration is obtained from the scale reading penetration of the handle, using the top edge of the independent stirrup as the line of reference. Penetration is measured to the nearest 1/4", and each reported value should be the average of at least three penetration tests. The depth of concrete to be tested should not be less than 8". This test is quickly made and is less prone to personal errors.  The ratio of slump to penetration is usually between 1.3 and 2.0.

Setting of concrete

 a) Definition: Setting is defined as the onset of rigidity in fresh concrete. It is different from hardening, which describes the development of useful and measurable strength. Setting precedes hardening although both are controlled by the continuing hydration of the cement.

 b) Abnormal setting

 False setting: If concrete stiffens rapidly in a short time right after mixing but restores its fluidity by remixing, and then set normally, the phenomenon is called false setting. The main reason causing the false setting is crystallization of gypsum. In the process of cement production, gypsum is added into blinker through inter-grinding. During grinding, the temperature can rise to about 120oC, thus causing the following reaction:

CSH2 →CSH1/2

The CSH1/2 is called plaster. During mixing, when water is added, the plaster will re-hydrate to gypsum and form a crystalline matrix that provides ‘stiffness’ to the mix. However, due to the small amount of plaster in the mix, very little strength will actually develop. Fluidity can be easily restored by further mixing to break up the matrix structure.

Flash setting: Flash setting is caused by the formation of large quantities of monosulfoaluminate or other calcium aluminate hydrates due to quick reactivities of C3A. This is a rapid set with the development of strength and thus is more severe than false setting. However, as we mentioned before, flash setting can be eliminated by the addition of3-5% gypsum into cement.  Thixotropic set is due to the presence of abnormally high surface charges on the cement particles. It can be taken care of by additional mixing. As the hydration reaction progresses with time, the concrete becomes less flowable, and the slump value will naturally decrease. However, if the slump value decreases at an abnormally fast rate, the phenomenon is called “slump loss”. It is often due to the use of abnormal setting cement, the unusually long time taken in the mixing and placing operations, or the high temperature of the mix (e.g., when concrete is placed under hot weather, or when ingredients have been stored under high temperature). In the last case, ice chips can be used to replace part of water to lower the temperature.

Placing, Compacting and Curing

Concrete should be placed as close to its final position as possible. To minimize segregation, it should not be moved over too long a distance. After concrete is placed in the formwork, it has to be compacted to remove entrapped air. Compaction can be carried out by hand rodding or tamping, or by the use of mechanical vibrators.  For concrete to develop strength, the chemical reactions need to proceed continuously. Curing refers to procedures for the maintaining of a proper environment for the hydration reactions to proceed. It is therefore very important for the production of strong, durable and watertight concrete. In concrete curing, the critical thing is to provide sufficient water to the concrete, so the chemical reaction will not stop. Moist curing is provided by water spraying, ponding or covering the concrete surface with wet sand, plastic sheets, burlaps or mats. Curing compounds, which can be sprayed onto the concrete surface to form a thin continuous sheet, are also commonly used. Loss of water to the surrounding should be minimized. If concrete is cast on soil subgrade, the subgrade should be wetted to prevent water absorption. In exposed areas (such as a slope), windbreaks and sunshades are often built to reduce water evaporation. For Portland cement concrete, a minimum period of 7 days of moist curing is generally recommended. Under normal curing (at room temperature), it takes one week for concrete to reach about 70% of its long-term strength. Strength development can be accelerated with a higher curing temperature. In the fabrication of pre-cast concrete components, steam curing is often employed, and the 7-day strength under normal curing can be achieved in one day. The mold can then be re-used, leading to more rapid turnover. If curing is carried out at a higher temperature, the hydration products form faster, but they do not form as uniformly. As a result, the long-term strength is reduced. This is something we need to worry about when we are casting under hot weather. The concrete may need to be cooled down by the use of chilled water or crushed ice. In large concrete structures, cooling of the interior (e.g., by circulation of water in embedded pipes) is important, not only to prevent the reduction of concrete strength, but also to avoid thermal cracking as a result of non-uniform heating/cooling of the structure.  After concrete is cast, if surface water evaporation is not prevented, plastic shrinkage may occur. It is the reduction of concrete volume due to the loss of water. It occurs if the rate of water loss (due to evaporation) exceeds the rate of bleeding. As concrete is still at the plastic state (not completely stiffened), a small amount of volume reduction is still possible, and this is accompanied by the downward movement of material. If this downward movement is restraint, by steel reinforcements or large aggregates, cracks will form as long as the low concrete strength is exceeded. Plastic shrinkage cracks often run perpendicular to the concrete surface, above the steel reinforcements. Their presence can affect the durability of the structure, as they allow corrosive agents to reach the steel easily. If care is taken to cover the concrete surface and reduce other water loss (such as absorption by formwork or subgrade), plastic shrinkage cracking can be avoided. If noticed at an early stage, they can be removed by re-vibration

WHAT ARE CLASSIFICATIONS OF CONCRETE?

 Based on unit weight   

ü Ultra-light concrete   <1,200 kg/m3

ü Lightweight concrete 1200- 1,800 kg/m3

ü Normal-weight concrete ~ 2,400 kg/m3

ü Heavyweight concrete > 3,200 kg/m3


 Based on strength (of cylindrical sample)

Ø Low-strength concrete < 20 MPa compressive strength

Ø Moderate-strength concrete   20 -50 MPa compressive strength

Ø High-strength concrete 50 - 200 MPa compressive strength

Ø Ultra high-strength concrete > 200 MPa compressive strength


 Based on additives: 

§  Normal concrete

§  Fiber reinforced concrete

§  Shrinkage-compensating concrete

§  Polymer concrete

WHAT ARE ADVANTAGES AND LIMITATIONS OF CONCRETE?

I.  Advantages:

a)  Economical: Concrete is the most inexpensive and the most readily available material. The cost of production of concrete is low compared with other engineered construction materials. Three major components: water, aggregate and cement. Comparing with steel, plastic and polymer, they are the most inexpensive materials and available in every corner of the world. This enables concrete to be locally produced anywhere in the world, thus avoiding the transportation costs necessary for most other materials.

b) Ambient temperature hardened material: Because cement is a low temperature bonded inorganic material and its reaction occurs at room temperature, concrete can gain its strength at ambient temperature.

c)  Ability to be cast: It can be formed into different desired shape and sizes right at the construction site.

d)  Energy efficiency: Low energy consumption for production, compare with steel especially. The energy content of plain concrete is 450-750 kWh / ton and that of reinforced concrete is 800-3200 kWh/ton, compared with 8000 kWh/ton for structural steel.

e)  Excellent resistance to water. Unlike wood and steel, concrete can harden in water and can withstand the action of water without serious deterioration. This makes concrete an ideal material for building structures to control, store, and transport water. Examples include pipelines (such as the Central Arizona Project, which provide water from Colorado River to central Arizona. The system contains 1560 pipe sections, each 6.7 m long and 7.5 m in outside diameter 6.4 m inside diameter), dams, and submarine structures. Contrary to popular belief, pure water is not deleterious to concrete, even to reinforced concrete: it is the chemicals dissolved in water, such as chlorides, sulfates, and carbon dioxide, which cause deterioration of concrete structures.

f) High temperature resistance: Concrete conducts heat slowly and is able to store considerable quantities of heat from the environment (can stand 6-8 hours in fire) and thus can be used as protective coating for steel structure.

g) Ability to consume waste: Many industrial wastes can be recycled as a substitute for cement or aggregate. Examples are fly ash, ground tire and slag.

h) Ability to work with reinforcing steel: Concrete and steel possess similar coefficient of thermal expansion (steel 1.2 x 10-5; concrete 1.0-1.5 x 10-5). Concrete also provides good protection to steel due to existing of CH (this is for normal condition). Therefore, while steel bars provide the necessary tensile strength, concrete provides a perfect environment for the steel, acting as a physical barrier to the ingress of aggressive species and preventing steel corrosion by providing a highly alkaline environment with about 13.5 to passivate the steel.

i)  Less maintenance required: No coating or painting is needed as for steel structures.

II.  Limitations and their improvements

Quasi-brittle failure mode: Concrete is a type of quasi-brittle material.

 Solution: Reinforced concrete

Low tensile strength: About 1/10 of its compressive strength.

Improvements: Fiber reinforced concrete; polymer concrete

c)  Low toughness: The ability to absorb energy is low. Improvements: Fiber reinforced concrete

d)  Low strength/BSG ratio (specific strength): Steel (300-600)/7.8.  Normal concrete (35-60) /2.3 Limited to middle-rise buildings. Improvements: Lightweight concrete; high strength concrete

e)  Formwork is needed: Formwork fabrication is laborer intensive and time consuming, hence costly Improvement: Precast concrete

f) Long curing time: Full strength development needs a month. Improvements: Steam curing

g) Working with cracks: Most reinforced concrete structures have cracks under service load. Improvements:  Pre-stressed concrete.

WHAT ARE FACTORS AFFECTING CONCRETE STRENGTH?

 Factors affecting concrete strength

Water/Cement Ratio

 In cement hydration, it has been pointed out that the density of hardened cement is governed by the water/cement ratio. With higher w/c ratio, the paste is more porous and hence the strength is lower.  Also, the strength continues to increase with decreasing w/c ratio only if the concrete can be fully compacted. For concrete with very low w/c ratio, if no water-reducing agent is employed, the workability can be so poor that a lot of air voids are entrapped in the hardened material. The strength can then be lower than that for concrete with higher w/c ratio. While w/c ratio is the most important parameter governing the strength of concrete, it is not the only parameter.

Age and Curing Condition

 Provided the concrete is properly cured, the strength increases with time due to the increased degree of hydration. The 7-day strength can range from 60 – 80% of the 28-day strength, with a higher percentage for a lower w/c ratio. After 28 days, the strength can continue to go up. Experimental data indicates that the strength after one year can be over 20% higher than the 28-day strength. The reliance on such strength increase in structural design needs to be done with caution, as the progress of cement hydration under real world conditions may vary greatly from site to site.

Aggregates

 For the same w/c ratio, mixes with larger aggregates give lower strength. This is due to the presence of a weak zone at the aggregate/paste interface, where cracking will first occur. With larger aggregates, larger cracks can form at the interface, and they can interact easier with paste cracks as well as other interfacial cracks. With the same mix proportion, rougher and more angular aggregates give higher strength than smooth and round aggregates.  However, with smooth aggregates, a lower w/c ratio can be employed to achieve the same workability. Therefore, it is possible to achieve similar strength with smooth and rough aggregates, by adopting slightly different w/c ratios.  For a fixed w/c ratio, the strength increases slightly with the aggregate/cement ratio. This is because aggregates are often denser than the cement paste. With less paste in the concrete, the overall density is increased.  For normal strength concrete, the aggregate strength is seldom a concern. However, in the development of high strength concrete, it is important to select aggregates with strength higher than that of the hardened paste.

Admixtures

Air-entraining agents decrease concrete strength by incorporation of bubbles. Set retarding and accelerating agents affect the early strength development but have little effect on ultimate strength. Incorporation of mineral admixtures increases ultimate strength through the pozzolanic reaction.

WHAT ARE THE PROPERTIES OF HARDENED CONCRETE?

Strength of hardened concrete 

Introduction 

A) Definition 

 Strength is defined as the ability of a material to resist stress without failure. The failure of concrete is due to cracking. Under direct tension, concrete failure is due to the propagation of a single major crack. In compression, failure involves the propagation of a large number of cracks, leading to a mode of disintegration commonly referred to as ‘crushing’. The strength is the property generally specified in construction design and quality control, for the following reasons: 

(1) It is relatively easy to measure, and (2) other properties are related to the strength and can be deduced from strength data. The 28-day compressive strength of concrete determined by a standard uniaxial compression test is accepted universally as a general index of concrete strength. 

Compressive strength and corresponding tests 

a) Failure mechanism  

The development of the vertical cracks results in expansion of concrete in the lateral directions. If concrete is confined (i.e., it is not allowed to expand freely in the lateral directions), growth of the vertical cracks will be resisted. The strength is hence increased, together with an increase in failure strain. In the design of concrete columns, steel stirrups are placed around the vertical reinforcing steel. They serve to prevent the lateral displacement of the interior concrete and hence increase the concrete strength. In composite construction (steel + reinforced concrete), steel tubes are often used to encase reinforced concrete columns. The tube is very effective in providing the confinement. 

 (b)  Specimen for compressive strength determination

 Note that the cube specimen is popular in U.K. and Europe while the cylinder specimen is commonly used in the U.S.   

i) Cube specimen 

  BS 1881: Part 108: 1983.Filling in 3 layers with 50 mm for each layer (2 layers for 100 mm cube). Strokes 35times for 150 mm cube and 25 times for 100 mm cube. Curing at 20±50C and 90% relative humility. 

  ii)  Cylinder specimen 

  ASTM C470-81. Standard cylinder size is 150 x 300 mm. Curing condition is temperature of 23±1.70C and moist condition. Grinding or capping is needed to provide level and smooth compression surface. 

(c) Factors influencing experiment results 

(i) End condition. Due to influence of platen restraint, cube's apparent strength is about 1.15 times of cylinders. In assessing report on concrete strength, it is important to know which type of specimen has been employed. 

(ii) Loading rate. The faster the load rate, the higher the ultimate load obtained. The standard load rate is 0.15 -0.34 MPa / s for ASTM and 0.2-0.4 MPa/s for BS. 

(iii)Size effect: The probability of having larger defects (such as voids and cracks) increases with size. Thus, smaller size specimen will give higher apparent strength. 

Tensile strength and corresponding tests 

It is important to notice that cracks form and propagate a lot easier in tension than in compression. The tensile strength is hence much lower than the compressive strength.

a) Direct tension test methods 

 Direct tension tests of concrete are seldom carried out because it is very difficult to control. Also, perfect alignment is difficult to ensure and the specimen holding devices introduce secondary stress that cannot be ignored. In practice, it is common to carry out the splitting tensile test or flexural test. 

b) Indirect tension test (split cylinder test or Brazilian test)

The splitting test is carried out by applying compression loads along two axial lines that are diametrically opposite. This test is based on the following observation from elastic analysis. Under vertical loading acting on the two ends of the vertical diametrical line, uniform tension is introduced along the central part of the specimen. The splitting tensile strength can be obtained using the following formula: 

Fst=2P/πLD

According to the comparison of test results on the same concrete, fst is about 10-15% higher than direct tensile strength, ft. 

c)  Flexural strength and corresponding tests 

Flexural test; 150 x 150 x 750 mm or 100 x 100 x 500 (Max. size of aggregate is less than 25 mm). From Mechanics of Materials, we know that the maximum tension stress should occur at the bottom of the constant moment region. 

The modulus of rapture can be calculated as: 

Fbt=PL/(bd*d)

This formula is for the case of fracture taking place within the middle one third of the beam. If fracture occurs outside of the middle one-third (constant moment zone), the modulus of rupture can be computed from the moment at the crack location according to ASTM standard, with the following formula. 

Fbt=3Pa/(bd*d)

However, according to British Standards, once fracture occurs outside of the constant moment zone, the test result should be discarded. Although the modulus of rupture is a kind of tensile strength, it is much higher than the results obtained from a direct tension test. This is because concrete can still carry stress after a crack is formed. The maximum load in a bending test does not correspond to the start of cracking, but correspond to a situation when the crack has propagated. The stress distribution along the vertical section through the crack is no longer varying in a linear manner. The above equations are therefore not exact. 

                         CONCRETE MIXES

Tables 1-6 show the most common mixes for different volumes of concrete and for different parts of concrete structures.


Table 1: volume of concrete produced from 50kg cement

            Mix                              volume of concrete

            1:3:6                               0.24

           1:2:4                                0.17

           1:5:3                                0.13


Table 2: quantity of materials required to produce 1m3 of concrete.

Mix           Cement (kg)                 Sand(m3)                     Aggregate(m3)

1:3:6    172                         0.36                             0.72

1:2:4    238                         0.33                              0.67

1:5:3   299                         0.13                              0.62


Table3: approximate volumes for buckets

Mix            Cement(buckets)        Sand(buckets)       Aggregate(buckets)    Water(buckets)

1:3:6             1                                 3                            6                           0.75

1:2:4             1                               2                            4                        0.5-0.75

1:5:3             1                         0.5                           3                            0.5


Table 4: water and cement ratio for normal slump

Mix                        water and cement ratio                 liter of water for 50kg cement

1:3:6                               0.7                                                    36

1:2:4                               0.55                                                    27

1:5:3                               0.5                                                   25


Table 5: mixes for different concrete structures

Mix        Structures                                              Cement(kg)   Sand(m3)  Aggregate(m3)   Water(litre)

1:3:6 Mass foundations,                                      50                  0.11      0.212               36

  1:3:6      Oversite slabs                                           50                 0.11             0.212              36

1:2:4 General reinforced concrete work           50                 0.07             0.413              30


Table6: maximum slump for concrete structures

Concrete structure                            Maximum slump(mm)

Mass foundation                                     76

Reinforced foundation                            100

Oversite concrete                                    125

Reinforced slabs and beams                    125

Reinforced column                                    100


CONCRETE AND CONCRETING

    INTRODUCTION

Concrete is a widely used construction material. It is produced by mixing properly proportioned quantities of aggregates, cement, and water by weight. Admixtures may be added in the mixture to produce concrete of specified quality. Concrete may be molded into any desired shape or size. Concrete is reinforced with steel to make a composite material that combines the ceramic properties of concrete with the tensile strength of steel. The integrity of reinforced cement concrete depends to a large extent on the reinforcing steel, plain or deformed.

Concrete in its plastic state must remain workable until it is placed in position and compacted. Hardened concrete must be durable against the process of deterioration. there are different types of concrete, such as shotcrete, light-/heavy weight concrete, ready-mixed concrete, high performance concrete, self-compacting concrete, polymer-modified concrete, fiber reinforced concrete. The influence of the elastic incompatibility of steel and concrete is avoidable in pre-stressed concrete.

There are specification and guideline for production transportation, and placing of concrete in the extreme hot/cold weather. Underwater concreting is a special operation that may have to be carried out in remote and difficult areas in unusual environment. Timber or metal forms are used to mould the concrete as per the equipment. Stripping of forms from the set concrete demands the same care that goes into the fabrication and erection of forms. Curing process is a very important factor in deterring the strength of concrete.

Quality of concrete is to be assured right from the stage of procurement of the ingredient of concrete including testing of water available at the site. Quality of concrete is to be checked by carrying out both destructive and non-destructive tests.

2.       DEFINITION OF CONCRETE

Concrete is a versatile construction material. It is defined as a properly proportioned, homogeneous, and dense mixture of fine and coarse aggregates, cement, and water with or without admixtures. The aggregates are considered as economic filler materials generally inert in nature. Cement and water comprised a continuous binder phase that, after hardening, holds the aggregates together into a compact mass having load-bearing capacity. There are many binders, such as asphalt, sulphur, epoxy resin, and so on but the unqualified term ‘concrete’ means that the binder is principally hardened cement paste, which is the product of the chemical reaction of the ordinary Portland cement and water. In common parlance, the term concrete implies ordinary Portland cement concrete despite wide acceptable of the blended cements.

An admixture is a material other than the essential ingredients such as water, aggregates, and Portland cement (ordinary/blended) used as an ingredient of concrete and added to it immediately before or during its production.

Concrete is the most widely used material, second only to water, which is used in larger quantities. Concrete is a material that has been used in some form since the ancient times because:

It possesses excellent resistance to water unlike wood and steel. It can be easily cast or formed into any predetermined shape or size. But the area of modern concrete dates from the middle of the nineteenth century with the advent of the first truly ’Portland’ cement. Although aggregates constitute about 70% of the produced concrete, it is the cement paste that is responsible for most of the good and bad qualities of concrete. For a given aggregate, physical and chemical characteristics of the cement paste determine the workability of plastic concrete such as strength, durability and dimensional stability. However, it has certain weakness. It is brittle and very poor in tension. Ductility and toughness are also poor.

Despite its deceptive uniformity, cement is not a unified chemical entity. It comprises at least four phases, which retain their different chemical identities during the hydration process. Concrete strength and durability are affected significantly by the relative proportion of these four phases of cement with some minor constituents of cement influencing concrete durability. It is well known that reinforced concrete is a composite material, combining the ceramic properties of concrete with the tensile strength of steel. The quality of both these components is essential to increase the maintenance free life of reinforced concrete structures in marine conditions, severe atmosphere pollution, and other extreme conditions.

3.       HISTORY

The word concrete comes from the Latin word" concretus " (meaning compact or condensed), the perfect passive participle of" concrescere ", from " con-" (together) and" crescere " (to grow) Perhaps the earliest known occurrence of cement was twelve million years ago, when a natural deposit formed after an occurrence of oil shale naturally combusted while adjacent to a bed of limestone. These ancient deposits were investigated in the 1960s and 1970s. On a human time-scale, lime mortars were used in Greece, Crete, and Cyprus in 800 BC. The Assyrian Jerwan Aqueduct (688 BC) made use of fully waterproof concrete. German archaeologist Heinrich Schliemann found concrete floors, which were made of lime and pebbles, in the royal palace of Tiryns, Greece, which dates roughly to 1400-1200 BC. Concrete was used for construction in many ancient structures.
The Romans used concrete extensively from300 BC to 476 AD, a span of more than seven hundred years. During the Roman Empire, Roman concrete (or opus caementicium) was made from quicklime, pozzolana and an aggregate of pumice. Its widespread use in many Roman structures, a key event in the history of architecture termed the Roman Architectural Revolution, freed Roman construction from the restrictions of stone and brick material and allowed for revolutionary new designs in terms of both structural complexity and dimension.

“Concrete as roman knew it, was a new and revolutionary material. Laid in the shape of arches, vaults and domes, it quickly hardened into a rigid mass, free from many of the internal thrusts and strains that troubled the builders of similar structures in stone or brick”

Modern tests show that opus caementicium had as much compressive strength as modern Portland-cement concrete (ca. 200 kg/cm 2). However, due to the absence of reinforcement, its tensile strength was far lower than modern reinforced concrete, and its mode of application was also different:

“Modern structural concrete differs from Roman concrete in two important details. First, its mi x consistency is fluid and homogeneous, allowing it to be poured into forms rather than requiring hand-layering together with the placement of aggregates, which in Roman practice, often consisted of rubble. Second, integral reinforcing steel gives modern concrete assemblies great strength in tension, whereas roman concrete could depend only upon the strength of the concrete bonding to resist tension.

The widespread use of concrete in many Roman structures has ensured that many survive to the present day. The Baths of Caracalla in Rome are just one example. Many Roman aqueducts and bridges have masonry cladding on a concrete core, as does the dome the Pantheon .After the Roman Empire, the use of burning lime and pozzolana was greatly reduced until the technique was all but forgotten between 500 AD and the 1300s. Between the 1300s until the mid-1700s, the use of cement gradually returned. The Canal du Midi was built using concrete in 1670, and there are concrete structures in Finland that date from the 16th century.

Perhaps the greatest driver behind the modern usage of concrete was the third Eddy stone Lighthouse in Devon, England. To create this structure, between 1756 and 1793, British engineer John Smeaton pioneered the use of hydraulic lime in concrete, using pebbles and powdered brick as aggregate. A method for producing Portland cement was patented by Joseph Aspdin on 1824. In 1889 the first concrete reinforced bridge was built, and the first large concrete dams were built in 1936, Hoover Dam and Grand Coulee Dam. Reinforced concrete was invented in 1849 by Joseph Monier.

4.       COMPOSITION OF CONCRETE

Concrete is a composite material composed of coarse granular material (the aggregate or filler) embedded in a hard matrix of material (the cement or binder) that fills the space between the aggregate particles and glues them together. We can also consider concrete as a composite material that consists essentially of a binding medium within which are embedded particles or fragments of aggregates. The simplest representation of concrete is:

Concrete = Filler + Binder.

 According to the type of binder used, there are many different kinds of concrete. For instance, Portland cement concrete, asphalt concrete, and epoxy concrete. In concrete construction, the Portland cement concrete is utilized the most.

The composition can be presented as follows  

Cement (+ Admixture) +Water→ Cement paste + fine aggregate →mortar+ coarse aggregate →concrete

 

Here we should indicate that admixtures are almost always used in modern practice and thus become an essential component of modern concrete. Admixtures are defined as materials other than aggregate (fine and coarse), water, fibre and cement, which are added into concrete batch immediately before or during mixing. The widespread use of admixture is mainly due to the many benefits made possible by their application. For instance, chemical admixtures can modify the setting and hardening characteristic of cement paste by influencing the rate of cement hydration. Water-reducing admixture can plasticize fresh concrete mixtures by reducing surface tension of water, air-entraining admixtures can improve the durability of concrete, and mineral admixtures such as pozzolans (materials containing reactive silica) can reduce thermal cracking. A detailed description of admixtures will be given in latter sections

There are many types of concrete available, created by varying the proportions of the main ingredients below. In this way or by substitution for the cementitious and aggregate phases, the finished products can be tailored to its application with varying strength, density, or chemical and thermal resistance properties.

Aggregate " consists of large chunks of material in a concrete mix, generally coarse gravel or crushed rocks such as limestone, or granite, along with finer materials such as sand.

Cement ", commonly Portland cement, and other cementitious materials such as fly ash and slag cement, serves as a binder for the aggregate. Water is then mixed with this dry composite, which produces a semi-liquid that workers can shape (typically by pouring it into a form). The concrete solidifies and hardens to rock-hard strength through a chemical process called hydration. The water reacts with the cement, which bonds the other components together, creating a robust stone-like material.

Chemical admixtures" are added to achieve varied properties. These ingredients may speed or slow down the rate at which the concrete hardens, and impart many other useful properties.

"Reinforcements” are often added to concrete. Concrete can be formulated with high compressive strength, but always has lower tensile strength. For this reason, it is usually reinforced with materials that are strong in tension (often steel).

“Mineral admixtures" are becoming more popular in recent decades. The use of recycled materials as concrete ingredients has been gaining popularity because of increasingly stringent environmental legislation, and the discovery that such materials often have complimentary and valuable properties. The most conspicuous of these are fly ash, a by-product of coal-fired power plants, and silica fume, a byproduct of industrial electric furnaces. The use of these materials in concrete reduces the amount of resources required as the ash and fume acts as a cementer placement. This displaces some cement production, an energetically expensive and environmentally problematic process, while reducing the amount of industrial waste that must be disposed of.

5.       THE MIXING DESIGN AND PROCESS

The mix design depends on the type of structure being built, how the concrete is mixed and delivered, and how it is placed to form the structure. Thorough mixing is essential for the production of uniform, high quality concrete. For this reason, equipment and methods should be capable of effectively mixing concrete materials containing the largest specified aggregate to produce uniform mixtures of the lowest slump practical for the work. Separate paste mixing has shown that the mixing of cement and water into a paste before combining these materials with aggregates can increase the compressive strength of the resulting concrete. The paste is generally mixed in a high-speed, shear-type mixer at a w/cm (water to cement ratio) of 0.30 to 0.45 by mass. The cement paste premix may include admixtures such as accelerators or retarders, superplasticizers, pigments, or silica fume. The premixed paste is then blended with aggregates and any remaining batch water and final mixing is completed in conventional concrete mixing equipment.

5.1. MATERIALS USED ON SITE

At the site there was concrete plant where all processes of mixing were done; here are some materials used at the site and some materials described below were not used for our site but because of their need in some cases of concrete mixing some was planned and available on site.

Cement

Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar and plaster. English masonry worker Joseph Aspdin patented Portland cement in 1824. It was named because of the similarity of its color to Portland limestone, quarried from the English Isle of Portland and used extensively in London architecture. It consists of a mixture of oxides of calcium, silicon and aluminum. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay and grinding this product (called clinker) with a source of sulfate (most commonly gypsum). In modern cement kilns many advanced features are used to lower the fuel consumption per ton of clinker produced.

Water

Combining water with a cementitious material forms a cement paste by the process of hydration. The cement paste glues the aggregate together, fills voids within it, and makes it flow more freely. A lower water to cement ratio yields a stronger, more durable concrete, while more water gives a freer-flowing concrete with a higher slump. Impure water used to make concrete can cause problems when setting or in causing premature failure of the structure. Hydration involves many different reactions, often occurring at the same time.

As the reactions proceed, the products of the cement hydration process gradually bond together the individual sand and gravel particles and other components of the concrete, to form a solid mass.

Reaction:
Cement chemist notation: C 3 S + H      C-S-H + CH

Standard notation: Ca3SiO 5 + H2O      (CaO) · (SiO 2) · (H 2O) (gel) + Ca (OH) 2

Balanced: 2Ca 3SiO5 + 7H 2O      3(CaO) ·2(SiO 2) ·4(H 2O) (gel) +3Ca (OH) 2

Aggregates

Crushed stone aggregate

Fine and coarse aggregates make up the bulk of a concrete mixture. Sand, natural gravel and crushed stone are used mainly for this purpose. Recycled aggregates (from construction, demolition and excavation waste) are increasingly used as partial replacements of natural aggregates, while a number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted. The presence of aggregate greatly increases the durability of concrete above that of cement, which is a brittle material in its pure state. Thus, concrete is a true composite material. Redistribution of aggregates after compaction often creates inhomogeneity due to the influence of vibration. This can lead to strength gradients. Decorative stones such as quartzite, small river stones or crushed glass are sometimes added to the surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers. In addition to being decorative, exposed aggregate adds robustness to a concrete driveway.

Reinforcement
Installing rebar in a floor slab during a concrete pour. Concrete is strong in compression, as the aggregate efficiently carries the compression load. However, it is weak in tension as the cement holding the aggregate in place can crack, allowing the structure to fail. Reinforced concrete adds steel reinforcing bars, steel fibers, glass fiber, or plastic fiber to carry tensile loads.

Chemical admixtures

In some cases of concrete at the site the use of admixture was needed, for example when the concrete was needed at the site of morocco the retarders was added in the concrete. Chemical admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. In normal use, admixture dosages are less than5% by mass of cement and are added to the concrete at the time of batching/mixing.  The common types of admixtures are as follows.

1. Accelerators speed up the hydration (hardening) of the concrete. Typical materials used are CaCl 2, Ca (NO 3) 2 and NaNO3. However, use of chlorides may cause corrosion in steel reinforcing and is prohibited in some countries, so that nitrates may be favored.

2. Retarders slow the hydration of concrete and are used in large or difficult pours where
partial setting before the pour is complete is undesirable. Typical polyol retarders are sugar,
sucrose, sodium gluconate, glucose, citric acid, and tartaric acid.

3. Air entrainments add and entrain tiny air bubbles in the concrete, which reduces damage during freeze-thaw cycles, increasing durability. However, entrained air entails a trade off with strength, as each 1% of air may decrease compressive strength 5%. Plasticizers increase the workability of plastic or "fresh" concrete, allowing it be placed more easily, with less consolidating effort. A typical plasticizer is lignosulfonate. Plasticizers can be used to reduce the water content of a concrete while maintaining workability and are sometimes called water-reducers due to this use. Such treatment improves its strength and durability characteristics. Superplasticizers (also called high-range water-reducers) are a class of plasticizers that have fewer deleterious effects and can be used to increase workability more than is practical with traditional plasticizers. Compounds used as superplasticizers include sulfonated
naphthalene formaldehyde condensate, sulfonated melamine formaldehyde condensate, acetone formaldehyde condensate and polycarboxylate ethers Pigments can be used to change the color of concrete, for aesthetics. Corrosion inhibitors are used to minimize the corrosion of steel and steel bars in concrete. Bonding agents are used to create a bond between old and new concrete (typically a type of polymer). Pumping aids improve pumpability, thicken the paste and reduce separation and bleeding.

6. EQUIPMENT AND MACHINERY USED

Ø  Mixer machine

Ø  Cement pump

Ø  Water pump

Ø  balances

Ø  Admixes pump

Ø  Computer

Ø  Generators

Ø  Bulldozers

Ø  Concrete mixer trucks

Ø  Concrete pump

 

7.       Skills and man power used

·         Engineers

·         Concrete specialists

·         Foremen

·         Students

·         Skilled and unskilled labourers

8.       SAFETY PRECAUTIONS

Because cement is dangerous for human body; during concrete work all workers at site were obliged to wear over coats, boots, and helmet and grooves to prevent them against any kind of harm.